Polymeric ligands, polymeric metallocenes, catalyst systems, pre

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

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526943, 502103, 502117, C08F 444, C08F 402, C08F 460, B01J 3100, B01J 3700

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active

060404027

ABSTRACT:
A polymerization process comprising contacting at least one olefin under polymerization conditions with a catalyst composition produced by combining an organoaluminoxane cocatalyst and a polymeric metallocene catalyst prepared by (1) forming a fluorine-containing polymer by (a) polymerizing a 2-vinyl fluorenyl compound or (b) polymerizing a fluorenyl compound by reacting it with chloro methyl methyl ether in the presence of zinc dichloride or aluminum trichloride; (2) reacting the fluorenyl-containing polymer with an alkali metal compound; and (3) reacting the product of step (2) with a transition metal-containing compound.

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