Method for the preparation of 1-aza-2-silacyclopentane compounds

Details Method for the preparation of 1-aza-2-silacyclopentane compounds Method for the preparation of 1-aza-2-silacyclopentane compounds

1993-06-23

1994-01-25

Shaver, Paul F.

Organic compounds -- part of the class 532-570 series

Organic compounds

Silicon containing

C07F 710

Patent

active

052817369

ABSTRACT:
The present invention relates to a method for the preparation of 1-aza-2-silacyclopentane compounds whose nitrogen is substituted by a hydrocarbon group or a heteroatom-containing hydrocarbon group. The method comprises effecting an intramolecular hydrosilylation reaction of a N,N-disubstituted aminosilane. In a preferred method, the intramolecular hydrosilylation reaction is conducted in the presence of a rhodium-containing catalyst.

REFERENCES:
patent: 5136064 (1992-08-01), King et al.
J. L. Speier, C. A. Roth, J. W. Ryan, J. Org. Chem, vol. 36, No. 21, 3121 (1971).
M. G. Voronkov, S. V. Kirpichenko, A. T. Abrosimova, A. I. Albanov J. Organomet. Chem., 406, 87-89 (1991).

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