Process to prepare a linear aldehyde

Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing

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568451, C07C 4550

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active

057103445

ABSTRACT:
The invention relates to a process for the preparation of linear aldehydes by hydroformylation of ethylenically unsaturated organic compounds in the presence of a catalyst system comprising a Group VIII metal and a bidentate organic ligand. The bidentate organic ligand is characterized in that it has two trivalent phosphorus atoms each containing at least one P--C or one P--N bond.

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Kenneth G. Moloy and Jeffrey L. Petersen, N-Pyrrolyl Phosphines: An Unexploited Class of Phosphine Ligands and Exceptional .pi.-Acceptor Character, J. Am. Chem. Soc. 1995, 117, 7696-7710, Feb. 28, 1995.

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