Preparation of N-substituted acrylamides

Details Preparation of N-substituted acrylamides Preparation of N-substituted acrylamides

1986-03-06

1987-06-23

Shaver, Paul F.

Organic compounds -- part of the class 532-570 series

Organic compounds

Amino nitrogen containing

544168, 546247, 548568, C07C10206

Patent

active

046754415

ABSTRACT:
This invention is directed to novel catalysts characterized as compounds of tin or zinc containing a direct metal-nitrogen bond. The novel catalysts are derived from a primary or secondary amine such as an alkyl amine, a heterocyclic amine, an aromatic amine, etc. The amine is reacted with a tin compound such as a tin chloride, a tin bromide, a tin oxide, or a tin alkoxide. Alternatively, the amine may be reacted with a zinc halide, a zinc alkoxide or an organozinc compound.
In another aspect of the present invention, the novel catalysts are used to catalyze the reaction of an acrylate or methacrylate ester with an amine in order to prepare N-substituted acrylamides or methacrylamides in good yield and with high selectivity.

REFERENCES:
patent: 2356476 (1944-08-01), Shappirio
patent: 2451436 (1948-10-01), Erickson
patent: 2529838 (1950-11-01), Erickson
patent: 2649438 (1953-08-01), Bruson
patent: 2719175 (1955-09-01), Couver et al.
patent: 2867566 (1959-01-01), Weinberg
patent: 2893857 (1959-07-01), De Pree
patent: 3461147 (1969-08-01), Noltes
patent: 3470220 (1969-09-01), Moedritzer et al.
patent: 3652671 (1972-03-01), Barron
patent: 3878247 (1975-04-01), Moss et al.
patent: 4022831 (1977-05-01), Spoerke
patent: 4031138 (1977-06-01), Nieh et al.
patent: 4206143 (1980-06-01), Wenzel et al.
patent: 4228102 (1980-10-01), Besecke et al.
patent: 4256665 (1981-03-01), McEntire
patent: 4256666 (1981-03-01), McEntire
patent: 4259259 (1981-03-01), McEntire
patent: 4287363 (1981-09-01), McEntire
patent: 4309358 (1982-01-01), Holyoke
patent: 4321411 (1982-03-01), Nakamura et al.
patent: 4358612 (1982-11-01), Gless
patent: 4492801 (1985-01-01), McEntire et al.
Chemical Abstracts 66 2641g (1967).
Chemical Abstracts 66 46631x (1967).
Chemical Abstracts 72 101195g (1979).
Chemical Abstracts 79 32337n (1973).
Chemical Abstracts 90 72289g (1979).
Chemical Abstracts 95 204660m (1981).
Chemical Abstracts 96 85083g (1982).
Chemical Abstracts 102 45495x (1985).
Erickson, "The Preparation and Stabilities of Some B-Dialkylaminopropionamides", Jr. Chem. Soc. 74, 6281-6282 (1952).
Sawyer, Organotin Compounds, Marcil Dekker Inc., NY pp. 507-521; 541-547; 553-555 (1971).

Affiliated with

Also associated with

Rating

Preparation of N-substituted acrylamides does not yet have a rating. At this time, there are no reviews or comments for this patent.

If you have personal experience with Preparation of N-substituted acrylamides, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Preparation of N-substituted acrylamides will most certainly appreciate the feedback.

Rate now

Comments { 0 }

Profile ID: LFUS-PAI-O-722585