Process for dimerizing acrylates to hexenedioates

Details Process for dimerizing acrylates to hexenedioates Process for dimerizing acrylates to hexenedioates

1983-04-18

1985-03-12

Trousof, Natalie

Organic compounds -- part of the class 532-570 series

Organic compounds

Carboxylic acid esters

502162, 502165, 502169, 502213, 502226, 502229, 502230, 502324, 502329, 502331, 562598, C07C 67343

Patent

active

045046743

ABSTRACT:
Alkyl acrylate esters are dimerized to dialkyl hexenedioates in the presence of a metal-treated ruthenium compound, an alcohol, optionally a phosphine, and optionally a carboxamide. The hexenedioate products are useful to prepare adipic acid.

REFERENCES:
patent: 2244645 (1941-06-01), Jacobson
patent: 3013066 (1961-12-01), Alderson
patent: 3074999 (1963-01-01), Rauhut et al.
patent: 3227745 (1966-01-01), McClure
patent: 3322819 (1967-05-01), Schreyer
patent: 3548021 (1970-12-01), Brattesane
patent: 3946066 (1976-03-01), Todd
patent: 3956358 (1976-05-01), Onsager

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