Chemistry of inorganic compounds – Sulfur or compound thereof – Oxygen containing
Patent
1979-02-15
1980-12-30
Thomas, Earl C.
Chemistry of inorganic compounds
Sulfur or compound thereof
Oxygen containing
423524, C01B 1782
Patent
active
042423210
ABSTRACT:
A process is described for separating SO.sub.2 from a current of gas containing the same, at least intermittently, in a concentration which is impermissibly high for discharge into the ambient atmosphere, with attendant production of sulfuric acid by the nitrogen oxide process, in which latter process the SO.sub.2 -containing gas initially flows through a dentriation zone, or first through a pretreatment zone forming a first sector of an SO.sub.2 -processinbg zone and then through the denitration zone, thereafter through the main sector of the SO.sub.2 -processing zone, and subsequently through a nitrogen oxide absorption zone, in the course of which flow it is brought into contact in at least one of the two sectors of the SO.sub.2 -processing zone with dilute acid having a H.sub.2 SO.sub.4 -concentration of less than 70% by weight (55.degree. Be) which acid is circulated through the sector concerned of this latter zone, while in the absorption zone the nitrogen oxides released in the denitration zone are absorbed by sulfuric acid, and nitrose-containing acid having a H.sub.2 SO.sub.4 -concentration of 70 to 80% by weight (55.degree. to 63.5.degree. Be) is drawn off from the absorption zone and fed into the denitration zone, which process further comprises
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Riegel Industrial Chemistry, 5th edition, Reinhold Publishing Corp., NY, NY, 1949, pp. 1-11.
Ciba-Geigy Corporation
Falber Harry
Straub Gary P.
Thomas Earl C.
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