Process for the photocatalytic isomerization of olefins utilizin

Chemistry: electrical and wave energy – Processes and products – Processes of treating materials by wave energy

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204162R, 585670, B01J 1912, C07C 523, C07C 525

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active

045043710

ABSTRACT:
A novel process for the isomerization of olefins which employs a photocatalytic mixed metal cluster, wherein a solution of the olefin and the cluster is irradiated causing the cluster to become catalytically active and to isomerize the olefin. The photocatalytic mixed metal cluster has the empirical formula:

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Hsieh et al., "New Nickel-Cobalt, Nickel-Iron and Nickel-Manganese Polynuclear Carbonyl Complexes", Journal of Organometallic Chemistry, 1971, pp. 125-132.

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