Method of producing primary amines in high yields

Details Method of producing primary amines in high yields Method of producing primary amines in high yields

1993-07-19

1994-02-08

Robinson, Allen J.

Organic compounds -- part of the class 532-570 series

Organic compounds

Amino nitrogen containing

564 8, 564 9, 564302, 564307, 564395, 564460, 564462, 564463, 564469, 564485, 564509, 568 1, 568 7, C07C 902, C07C20400

Patent

active

052849767

ABSTRACT:
A novel process for producing hindered and unhindered primary amines represented by the formula RNH.sub.2 and R*NH.sub.2 in high yields from novel intermediates RBMe.sub.2 or R*BMe.sub.2 wherein R is an organo group, R* is a chiral organo group. attached to boron, B is boron and Me is methyl.

REFERENCES:
Brown et al. "The Reaction of Organoboranes with Chloramine and with Hydroxylamine-O-sulfonic Acid", etc. J. Amer. Chem. Soc. 1964, 86, 3565-6.

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