Dehydrogenation of naphthene hydrocarbons

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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260668D, 2606833, 26068368, 208139, 252466PT, C07C 536

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active

041395700

ABSTRACT:
Naphthene hydrocarbons are dehydrogenated by contacting them, at dehydrogenation conditions, with a catalytic composite comprising a combination of catalytically effective amounts of a platinum group component, a cobalt component, and a bismuth component with a porous carrier material. A specific example of the preferred nonacidic catalytic composite for use in this dehydrogenation method is a combination of a platinum group component, a cobalt component, a bismuth component, and an alkali or alkaline earth component with a porous carrier material in amounts sufficient to result in a composite containing about 0.01 to about 2 wt. % platinum group metal, about 0.05 to about 5 wt. % cobalt, about 0.01 to about 5 wt. % bismuth and about 0.1 to about 5 wt. & alkali metal or alkaline earth metal.

REFERENCES:
patent: 3655747 (1972-04-01), Sennewald et al.
patent: 3759823 (1973-09-01), Davies et al.
patent: 4048245 (1977-09-01), Pollitzer et al.

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