Phenylethynyl amine

Organic compounds -- part of the class 532-570 series – Organic compounds – Amino nitrogen containing

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564315, 564329, 564430, C07C22522, C07C21790, C07C31736

Patent

active

055999930

ABSTRACT:
Four phenylethynyl amine compounds--3 and 4-aminophenoxy-4'-phenylethynylbenzophenone, and 3 and 4-amino-4'-phenylethynylbenzophenone--were readily prepared and were used to endcap imide oligomers. Phenylethynyl-terminated amide acid oligomers and phenylethynyl-terminated imide oligomers with various molecular weights and compositions were prepared and characterized. These oligomers were cured at 300.degree. C. to 400.degree. C. to provide crosslinked polyimides with excellent solvent resistance, high strength and modulus and good high temperature properties. Adhesive panels, composites, films and moldings from these phenylethynyl terminated imide oligomers gave excellent mechanical performance.

REFERENCES:
patent: 5145937 (1992-09-01), Hergenrother
Bryant et al, Polymer Prepr., vol. 34, No. 1 (Mar. 5, 1993) pp. 566-567.

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