Method of electrolysis of brine

Chemistry: electrical and wave energy – Processes and products – Electrostatic field or electrical discharge

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Details

204129, C25B 126, C25B 102

Patent

active

039545814

ABSTRACT:
Disclosed is a method of electrolyzing alkali metal chloride brine in an electrolytic cell having an anolyte chamber containing an anode and a catholyte chamber containing a steel cathode, separated from the anolyte chamber by an asbestos diaphragm. Brine is fed to the anode chamber, a voltage is imposed across the cell, chlorine is evolved at the anode, and hydrogen is evolved at the cathode. According to the disclosed method, the hydrogen overvoltage is reduced by feeding an hydroxy carboxylic acid to the electrolytic cell. Additionally, a phosphorous containing compound and a surfactant may be added to the cell to further reduce the hydrogen overvoltage.

REFERENCES:
patent: 3711388 (1973-01-01), Gritzner

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