Double metal cyanide catalysts containing functionalized polymer

Catalyst – solid sorbent – or support therefor: product or process – Catalyst or precursor therefor – Organic compound containing

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502175, 502200, B01J 3100, B01J 3102, B01J 3106

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active

057144281

ABSTRACT:
Double metal cyanide (DMC) catalysts useful for epoxide polymerizations are disclosed. The catalysts comprise a DMC compound, an organic complexing agent, and from about 2 to about 80 wt. % of a functionalized polymer or a water-soluble salt derived from the polymer. The catalysts are easy to prepare and isolate, are substantially non-crystalline, and have high activity for polymerizing epoxides. Polyols made from the catalysts have exceptionally low unsaturations, low viscosities, and reduced levels of high molecular weight polyol tail.

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