Preparation of polymeric acetal carboxylates using molecular sie

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Mixing of two or more solid polymers; mixing of solid...

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528230, 528245, 528246, 528494, C08F28306, C08G 600

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active

042244200

ABSTRACT:
The alkali metal, ammonium and alkanol ammonium salts of polymeric acetal carboxylates are stable detergent builders under laundry use conditions but depolymerize in acid media, making the polymer fragments more readily biodegradable in waste streams. Such polymeric acetal carboxylates can now be made by a process which comprises bringing together in a reaction zone under polymerization conditions an ester of glyoxylic acid and a molecular sieve, and adding an alkyl vinyl ether to the resulting polymer in the presence of the molecular sieve to stabilize the polymer against rapid depolymerization in alkaline solution. The preferred alkyl vinyl ether is ethyl vinyl ether.

REFERENCES:
patent: 4140676 (1979-02-01), Crutchfield et al.
patent: 4144226 (1979-03-01), Crutchfield et al.
patent: 4146495 (1979-03-01), Crutchfield et al.

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