Process for the production of aldehydes and alcohols from olefin

Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing

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568909, 568454, C07C 4510

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active

042242550

ABSTRACT:
Oxygenated compounds are prepared by reacting olefinically unsaturated compounds with carbon monoxide and hydrogen in the presence of a hydroformylation catalyst with suppression of the olefin hydrogenation side reaction if an acid is used in the reaction mixture. Typically, o-phthalic acid suppresses the formation of hexane and n-propanol, respectively, when 1-hexene and allyl alcohol are hydroformylated.

REFERENCES:
patent: 3239566 (1966-03-01), Slaugh et al.
patent: 3274263 (1966-09-01), Greene et al.
patent: 3825601 (1974-07-01), Rennick
patent: 3917661 (1975-11-01), Pruett et al.

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