Polymerization using benzenediazonium tetrafluoroborate/titanium

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

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526119, 526133, 526134, 526352, C08F 464, C08F 1000

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active

045309825

ABSTRACT:
A catalyst system is provided comprising a titanium catalyst component produced by contacting a benzenediazonium tetrafluoroborate with a titanium tetrahalide such as titanium tetrachloride and a cocatalyst. Preferred cocatalysts are organoaluminum compounds. The catalyst system of this invention is broadly suitable for this polymerization of 1-olefins and is particularly suited for the production of high molecular weight ethylene polymers.

REFERENCES:
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patent: 3303239 (1967-02-01), Cleary et al.
patent: 3513147 (1970-05-01), Fodor et al.
patent: 3514433 (1970-05-01), Nicco
patent: 4151110 (1979-04-01), Cesca et al.
patent: 4210729 (1980-07-01), Hermans

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