Fluoroacrylate ester, polymer thereof, and process of making the

Details Fluoroacrylate ester, polymer thereof, and process of making the Fluoroacrylate ester, polymer thereof, and process of making the

1985-02-26

1986-03-25

Michl, Paul R.

Organic compounds -- part of the class 532-570 series

Organic compounds

Carboxylic acid esters

C07C 6952

Patent

active

045785082

ABSTRACT:
A fluoroacrylate ester monomer having the formula: ##STR1## wherein R.sub.1 and R.sub.2 are independently selected from the group consisting of saturated aliphatic hydrocarbons having from 1 to about 3 carbon atoms and R.sub.3 is selected from the group consisting of hydrogen and methyl. The monomer has a water-repellent "umbrella" of 3 gem bis trifluoromethyl groups around the acrylate monomer which do not interfere with the acrylate properties. Polymerization of the monomer results in a stable, exceptionally hydrophobic, linear thermoplastic polymer. The invention also includes processes for making the monomer from a diether halide and certain novel intermediates.

REFERENCES:
"Umbrella Fluoroacrylic Polymers": Griffith, James R.: Chemical Abstracts 101: 23971k.

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