Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing
Patent
1989-02-16
1990-06-12
Moyer, Donald B.
Organic compounds -- part of the class 532-570 series
Organic compounds
Oxygen containing
C07C17800, C07C17906
Patent
active
049335014
ABSTRACT:
Terpene peroxides of formula: ##STR1## in which R denotes a tertiary alkyl radical substituted, if desired, by one or more phenyl radicals, a cycloalkyl radical or a trialkylsilyl radical, R.sub.1, R.sub.2 and R.sub.3, which are identical or different, each denote hydrogen or an aliphatic radical optionally containing one or more double or triple bonds and optionally substituted, and R.sub.4 denotes an aliphatic radical optionally containing one or more double or triple bonds and optionally substituted or R.sub.3 denotes hydrogen and R.sub.2 and R.sub.4 together form an alkylene radical which may be substituted by one or more methyl radicals, are obtained by reaction of a hydroperoxide of formula R--OOH with a compound of formula: ##STR2## the operation being carried out in a basic aprotic solvent.
REFERENCES:
patent: 2516649 (1950-07-01), Rust et al.
patent: 4133835 (1979-01-01), Bafford et al.
J. Org. Chem., vol. 51, No. 10, 1986, pp. 1790-1793.
Tetrahedron, vol. 41, No. 19, 1985, pp. 4047-4056.
Journal of Organic Chemistry of the USSR, vol. 23, No. 9, partie Sep. 1, 1987, pp. 1640-1642.
Moyer Donald B.
Plue Karen E.
Rhone-Poulenc Sante
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