Method for monitoring sulfates and chlorides at low concentratio

Chemistry: electrical and wave energy – Processes and products – Processes of treating materials by wave energy

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20415319, 204416, 204419, G01N 27333

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active

050026445

ABSTRACT:
A method for monitoring low anion concentrations, and particularly sulfate concentrations in aqueous solutions is provided which includes the steps of adjusting the pH of the solution to substantially reduce the presence of hydroxides therein, mixing a nonionic solvent with the solution selected from the group consisting of alcohols, aldehydes, ketones, nitriloes and other water soluble organic compounds which do not contain sulfonate groups, exposing the solution and solvent mixture to an electrode selective for sulfate ions, exposing the mixture to a counter electrode and measuring the difference in voltage across the electrodes. A chilling apparatus may be added to reduce solvent consumption and lower the detection limit.

REFERENCES:
patent: 3563874 (1971-02-01), Ross et al.
patent: 3672962 (1972-06-01), Frant et al.
Durst, "Ion-Selective Electrodes", (1969), p. 101.
Orion Research, Analytical Methods Guide, (1972), pp. 4, 13, 14.

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