Organic compounds -- part of the class 532-570 series – Organic compounds – Four or more ring nitrogens in the bicyclo ring system
Patent
1984-07-06
1987-06-02
Bond, Robert T.
Organic compounds -- part of the class 532-570 series
Organic compounds
Four or more ring nitrogens in the bicyclo ring system
544368, 546198, 548167, 548168, 540544, 540553, 540575, 540602, C07D27780
Patent
active
046705562
ABSTRACT:
This invention relates to a process for the production of benzothiazolyl sulphenamides corresponding to the following general formula: ##STR1## in which a corresponding 2-mercaptobenzothiazole or a dibenzothiazolyl-2,2'-disulphide is reacted with a primary or secondary amine at temperatures of from 0 to 100.degree. C. in the presence of ammonia, oxygen, a copper-containing catalyst and a reaction medium containing an excess of the primary or secondary amine or of a mixture of that amine with water and/or a water-miscible organic solvent.
Benzothiazolyl sulphenamides are valuable vulcanization accelerators.
REFERENCES:
patent: 3549650 (1970-12-01), D'Amico
patent: 4182873 (1980-01-01), Janin
patent: 4258197 (1981-03-01), Toukan
Bergfeld Manfred
Eisenhuth Ludwig
Zengel Hans
Akzo NV
Bond Robert T.
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