Olefine polymerization with supported catalysts

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

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252455R, 252463, 252464, 252465, 526 95, 526101, 526107, 526352, 526907, C08F 462, C08F 466, C08F 468

Patent

active

042398720

ABSTRACT:
Polymerization catalysts are prepared by impregnation of a silica or aluminum support with a vanadium, titanium and/or chromium salt decomposable upon calcination to the oxide, calcining the impregnated support at about 500.degree.-700.degree. C., impregnating the calcined support with a solution of aluminum hydride and heating the resultant material to about 300.degree. C.-500.degree. C. in hydrogen. The catalyst is extremely active for the polymerization of lower molecular weight olefins such as ethylene and ethylene-propylene mixtures.

REFERENCES:
patent: 2912419 (1959-11-01), Peters et al.
patent: 3146209 (1964-08-01), Byrne et al.
patent: 3526601 (1970-09-01), Fotis et al.
patent: 3897364 (1975-07-01), Colombo et al.

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