Preparation of nitriles of fused ring pyridine derivatives

Details Preparation of nitriles of fused ring pyridine derivatives Preparation of nitriles of fused ring pyridine derivatives

1985-09-16

1988-02-23

Daus, Donald G.

Organic compounds -- part of the class 532-570 series

Organic compounds

Heterocyclic carbon compounds containing a hetero ring...

546 79, 546 93, 546101, 546104, 546110, 546112, 546173, 546177, C07D21548

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047271493

ABSTRACT:
Nitriles of fused ring pyridine compounds such as 5,6,7,8-tetrahydroquinolines are prepared from metal derivatives of the starting compounds such as 8-litho-5,6,7,8-tetrahydroquinolines which have been prepared by treating a 5,6,7,8-tetrahydroquinoline with a metal amide prepared in situ from a metal alkyl and an N-benzylidine-N-alkylamine.

REFERENCES:
patent: 4526970 (1985-07-01), Shepherd
patent: 4529798 (1985-07-01), Shepherd
patent: 4539406 (1985-09-01), Crossley
Emmling et al., J. Org. Chem., vol. 24 (1959), p. 657.
Stowell et al., Synthesis, (1974), pp. 127-128.
Ruckdeschel et al., Pharmazie, vol. 31 (1976), p. 374.
Anderson et al, Can. J. Chem., vol. 49 (1971), p. 2315.
Levine et al., J. Org. Chem., vol. 39, (1974), p. 3556.
Lettre et al., Chem. Berichte, vol. 85, (1952), p. 397.

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