Preparation of secondary amines

Organic compounds -- part of the class 532-570 series – Organic compounds – Amino nitrogen containing

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564305, 564306, 564309, 564336, 564340, 564343, 564346, 564355, 564374, 564378, 564389, 564391, 564395, 564396, 564399, 564401, 564408, 564446, 564447, 564467, C07C 8518

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043179320

ABSTRACT:
A process for forming amines by contacting, in a liquid media, an olefinic compound, carbon monoxide, water, and ammonia in the presence of a rhodium atom containing compound selected from metallic rhodium, rhodium salts, rhodium oxides, and rhodium carbonyls and ligands thereof at a temperature of from 50.degree. to 250.degree. C. and at a pressure of from about 10 to about 300 atmospheres.

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Houben-Weyl, "Methoden der Organischen Chemie", 4th Ed., vol. 11/1, pp. 994-999 (1957).

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