Process for the preparation of alpha-substituted epoxide compoun

Details Process for the preparation of alpha-substituted epoxide compoun Process for the preparation of alpha-substituted epoxide compoun

1975-09-25

1977-12-20

Milestone, Norma S.

Chemistry of carbon compounds

Miscellaneous organic carbon compounds

C-metal

C07D30122

Patent

active

040641465

ABSTRACT:
An alpha-substituted epoxide, represented by the formula: ##STR1## wherein R, R' and R"' are alkyl having up to 12 C atoms and R" is hydrogen, is prepared by oxidizing, with molecular oxygen, the corresponding alcohol, represented by the formula: ##STR2## wherein R, R', R" and R"' have the meaning given above, in the presence of a catalyst consisting of a monovalent copper complex.

REFERENCES:
patent: 1925317 (1933-09-01), Fuchs
patent: 2434631 (1948-01-01), Winkler et al.
Jour. Am. Chem. Soc., vol. 36, p. 533.

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