Process for preparing oligomers and telechels having carboxy-pip

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – From reactant having a nitrogen atom directly bonded to the...

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528372, 544387, 544360, 544357, 25218228, C08G 6362, C09K 300, C07D24104

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047586524

ABSTRACT:
A process for preparing oligomers and telechels of poly(carboxy-piperazine) and new oligomers the telechels of poly(carboxy-piperazine), wherein the process involves condensation of piperazine or piperazine-N-carboxylic acid esters or their reaction with piperazine or piperidine derivatives to form an intermediate which is reacted with diphenyl carbonate in the presence of a tertiary amine.

REFERENCES:
patent: 2717896 (1955-09-01), Goldman
patent: 3130179 (1964-04-01), Cotter
patent: 3954770 (1976-05-01), Mayerhoefer et al.
patent: 4165424 (1979-08-01), Hermans
Chemical Abstracts, vol. 82, Nr. 17, Apr. 28, 1975, Columbus, Ohio, M. I. Doroklova, "Synthesis of 1-methyl-piperazine", p. 511 (112033n).
Australian Journal of Chemistry, vol. 19, 1966, Melbourne, D. E. Rivett et al., "Some Reactions of 1,4-Bischlorocarbonylpiperazine", pp. 869-875.
Die Makromolekulare Chemie, Bol. 187, Nr. 6, Jun. 1986.
R. Schwalm et al., "Syntheses of Telechelic Oligo-and poly(carboxypiperazine)s", pp. 1415-1422.

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