Compositions – Preservative agents – Anti-oxidants or chemical change inhibitants
Patent
1981-04-13
1983-09-20
Cooper, Jack
Compositions
Preservative agents
Anti-oxidants or chemical change inhibitants
252439, 252466PT, 4232135, B01J 2310, B01J 2356, B01J 2702
Patent
active
044055064
ABSTRACT:
A refractory inorganic oxide support is impregnated with a mixture of a platinum sulfito complex solution and a rhodium nitrate solution or with a mixture of a platinum sulfito complex solution, a rhodium nitrate solution, and a rhodium sulfito complex solution and the impregnated support is activated. The method produces a catalyst which has a maximum platinum concentration within 20 microns of the external surface of the support and at least about 70 percent of the total platinum located within 100 microns of the external surface of the support. The catalyst also has at least about 30 percent of the total rhodium located within 20 microns of the external surface of the support and at least about 40 percent of the total rhodium located at 20 to 100 microns from the external surface of the support.
REFERENCES:
patent: 3932309 (1976-01-01), Graham et al.
patent: 4102819 (1978-07-01), Petrow et al.
patent: 4128506 (1978-12-01), Hegedus et al.
patent: 4153579 (1979-05-01), Summers et al.
Bailar, J. C. et al., Comprehensive Inor. Chem; vol. 3, Pergamon Press Ltd., Oxford, U.K., 1973; pp. 1248 & 1341.
Collins Mark T.
Cooper Jack
W. R. Grace & Co.
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