Process for purifying an aqueous, hydrogen sulfide-scrubbing sol

Liquid purification or separation – Processes – Making an insoluble substance or accreting suspended...

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210713, 210722, 210765, 210909, 210912, 423 55, 423 67, 423221, 423226, 4235731, C01G 3100, C02F 172

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active

048836010

ABSTRACT:
A process for purifying an aqueous, hydrogen sulfide-scrubbing solution which contains a water-soluble transition metal component, such as a vanadium component or an iron component, in addition to at least one water-soluble organic compound, such as an aromatic sulfonate or an alkanolamine, in which the scrubbing solution is mixed with particles of a spent solid catalyst containing molybdenum and aluminum and a basic aqueous solution, preferably a solution comprising sodium aluminate, to form a slurry which is subsequently contacted with an oxygen-containing gas under conditions such that the molybdenum in the catalyst is solubilized. Thereafter, molybdenum is precipitated from the solution along with the water-soluble transition metal component and a wastewater substantially free of the transition metal component and the organic compound originally present in the scrubbing solution is recovered.

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