Process for catalytic oxidation of olefins to form hydroperoxide

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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Details

260618C, 260599, 260590R, 252429C, 252431N, C07C 2900, C07C17900

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active

040340473

ABSTRACT:
Polymeric complexes formed between a thermally-condensed polyacrylonitrile polymer and transition metal salts, including rare earth metals, have been found to be effective catalysts for the oxidation of compounds containing activated carbon-hydrogen bonds such as olefins, or secondary and tertiary alkylaromatics, to form valuable oxidation products, particularly hydroperoxides or their decomposition products.

REFERENCES:
patent: 2751418 (1956-06-01), Enos
patent: 3200100 (1965-08-01), Dennstedt
patent: 3301905 (1967-01-01), Riemenschneider et al.

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