Preparation of N-phenyl-N-alkylphenylenediamines

Organic compounds -- part of the class 532-570 series – Organic compounds – Amino nitrogen containing

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564397, 564398, C07C 8508

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active

043049397

ABSTRACT:
The desired compounds, namely, N-phenyl-N'-alkylphenylenediamines, are prepared by the reductive alkylation of a nitrogen-containing diphenylamine and a ketone in the presence of hydrogen and a hydrogenation catalyst. The desired product may be obtained in a more economical way when effecting the process in a continuous manner by utilizing an organic solvent for the reaction which comprises an ether compound such as a monoether of a dihydric alcohol, a diether of a dihydric alcohol, or a cyclic diether.

REFERENCES:
patent: 2809994 (1957-10-01), Hinckley
patent: 4140718 (1979-02-01), Symon
patent: 4155936 (1979-05-01), Sturm
Morrison et al., "Organic Chemistry", 2nd Edition, p. 492 (1966).

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