N-alkyl-N-alkoxycarboxamides and methods of use in prostaglandin

Details N-alkyl-N-alkoxycarboxamides and methods of use in prostaglandin N-alkyl-N-alkoxycarboxamides and methods of use in prostaglandin

1998-12-18

2000-01-18

Gerstl, Robert

Organic compounds -- part of the class 532-570 series

Organic compounds

Hydroxamate esters or chalcogen analogues thereof

556419, C07C40500

Patent

active

060159227

ABSTRACT:
Novel N-alkyl-N-alkoxycarboxamides useful for prostaglandin synthesis are disclosed. Also disclosed are novel synthetic methods for preparing the novel intermediates of the present invention.

REFERENCES:
Buchmann et al., "Synthesis of a Chemically and Metabolically Stable", Tetrahedron Letters, Vol. 31, No. 24, pp. 3425-3428 (1990).
Cooper et al., "Synthesis of the Four Stereoisomers of Enprostil.sup.1,2 ", Journal of Organic Chemistry, vol. 58, pp. 4280-4286 (1993).
Mills et al., "Diastereospecific, Non-Racemic Synthesis of the C.20-C.34 Segment of the Novel Immunosuppressant FK-506", Tetrahedron Letters, vol. 29(3), pp. 281-284 (1988).
Schaaf et al., "Synthesis of 11.alpha.,9.alpha.-Epoxymethanothromboxane A.sub.2 : A Stable, Optically Active TxA.sub.2 Agonist", J. Am. Chem. Soc., vol. 103, pp. 6502-6505 (1981).

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