Method for the preparation of a triorganosilylated 2,3-unsaturat

Details Method for the preparation of a triorganosilylated 2,3-unsaturat Method for the preparation of a triorganosilylated 2,3-unsaturat

1980-09-11

1981-07-28

Shaver, Paul F.

Organic compounds -- part of the class 532-570 series

Organic compounds

Silicon containing

C07F 718

Patent

active

042811481

ABSTRACT:
The invention provides a novel method for the preparation of a triorganosiloxy derivative of a 2,3-unsaturated alcohol which is a useful intermediate compound for the synthetic preparation of various kinds of organic compounds. The method comprises reacting an oxirane compound having at least 3 carbon atoms in a molecule, of which the carbon atom adjacent to the oxirane ring has at least one hydrogen atom directly bonded thereto, with a triorganosilyl trifluoromethanesulfonate in the presence of an amine compound.

REFERENCES:
patent: 2746956 (1956-05-01), Speier
patent: 2766103 (1956-10-01), Nielsen et al.
patent: 3453307 (1969-07-01), Nitzsche et al.

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