Fluorinated benzene manufacturing process

Organic compounds -- part of the class 532-570 series – Organic compounds – Halogen containing

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C07C 1720

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active

060875437

ABSTRACT:
A process is disclosed for producing fluorinated benzene. The process involves (a) contacting chlorobenzene starting material with a metal fluoride composition of the formula (AgF)(MF.sub.2).sub.x (where M is Mn, Fe, Co, Ni, Cu, Zn or a mixture thereof and x is a number between 0 and 1) at a temperature above 175.degree. C. sufficient to remove the chlorine substituent from the starting material and to transfer F from the metal fluoride composition to the starting material (thereby producing a reduced metal fluoride composition comprising a silver component of the formula AgF.sub.1-y where y is a number from 0.01 to 1); (b) oxidizing the reduced metal fluoride composition from (a) in the presence of HF to regenerate the metal fluoride mixture composition of the formula (AgF)(MF.sub.2).sub.x ; and (c) recycling regenerated metal fluoride composition of (b) to (a).

REFERENCES:
patent: 3277192 (1966-10-01), Fielding et al.
patent: 4394527 (1983-07-01), Fischer et al.

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