Supported catalysts containing rhenium and aluminium, preparatio

Catalyst – solid sorbent – or support therefor: product or process – Catalyst or precursor therefor – Organic compound containing

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502150, 502168, 502170, 502172, 502355, 502102, 585647, 585643, B01J 3100, C07C 600

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active

057474087

ABSTRACT:
The present invention concerns new catalysts based on compounds containing both rhenium and aluminum, which are deposited on an organic or inorganic support. The compounds of rhenium and aluminum correspond to the general formula:
in which R is a hydrocarbyl residue, for example alkyl, cycloalkyl, alkenyl, aryl, and aryl or cycloalkyl which are substituted, containing from 1 to 40 carbon atoms, which residue can be substituted by alkoxy groups or by halogens, L is the synthesis solvent, x is equal to 0 or 1 and n is an integer of from 1 to 10. The invention also concerns the preparation of such catalysts and the use thereof for the metathesis of olefins.

REFERENCES:
patent: 4454368 (1984-06-01), Banks
patent: 4943397 (1990-07-01), Johnson
patent: 5135958 (1992-08-01), Radlowski et al.
patent: 5218131 (1993-06-01), Warwel et al.
patent: 5342985 (1994-08-01), Hermann et al.
patent: 5405924 (1995-04-01), Kelsey
patent: 5449852 (1995-09-01), Chauvin et al.

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