Process for the preparation of 3-halo-and pseudohalo-alkylsilane

Details Process for the preparation of 3-halo-and pseudohalo-alkylsilane Process for the preparation of 3-halo-and pseudohalo-alkylsilane

1995-10-25

1997-04-01

Shaver, Paul F.

Organic compounds -- part of the class 532-570 series

Organic compounds

Silicon containing

556414, 556415, 552 4, C07F 708, C07F 710

Patent

active

056167628

ABSTRACT:
3-Halo- and pseudohalo-alkylsilane esters are prepared by reacting an allyl X compound or a compound containing an allyl X structure with a hydridosilane ester in the presence of an iridium catalyst prepared under specific conditions and/or the reaction medium containing a 0.01-100 mol % excess of the allyl X compound or compound containing the allyl X unit relative to the amount of hydridosilane ester reactant.

REFERENCES:
patent: 3296291 (1967-01-01), Chalk et al.
patent: 3564266 (1971-02-01), Klotz, Jr.
patent: 4658050 (1987-04-01), Quirk
patent: 5523436 (1996-06-01), Dauth et al.
Tanaka M. et al, "Ruthenium Complex-Catalyzed Hydrosilylation of Allyl Chloride with Trimethoxysilane", Chemical Abstracts, vol. 119, No. 17, Oct. 25, 1993, p. 802.
Kopylova, L.I. et al, "Iridium Complexes in the Hydrosilylation of Unsaturated Compounds", Russian Journal of General Chemistry, vol. 63, No. 10, Oct. 1993, pp. 2257-2266.
Belyakova Z. V. et al, "Patterns of Behavior in the Reactions of Hydride Silanes with Allyl Chloride", Zhurnal Obshchei Khimii, vol. 44, No. 11, Nov. 1974, pp. 2439-2442.

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