Use of dimethyl substituted oxymethyl cyclohexane derivatives fo

Details Use of dimethyl substituted oxymethyl cyclohexane derivatives fo Use of dimethyl substituted oxymethyl cyclohexane derivatives fo

1995-06-27

1996-11-19

Mullis, Jeffrey C.

Drug, bio-affecting and body treating compositions

Preparations characterized by special physical form

Biocides; animal or insect repellents or attractants

424 84, 431321, A01N 2508

Patent

active

055760104

ABSTRACT:
Described is a method for repelling insects by use of oxymethyl cyclohexane derivatives of the structure ##STR1## wherein Z is methylene; n is 0 or 1; each of the wavy lines represents a carbon-carbon single bond or no bond; the dashed line represents a carbon-carbon double bond or a carbon-carbon single bond; each of R.sub.2, R.sub.5, R.sub.6, R.sub.7 and R.sub.8 are the same or different and each represents hydrogen or methyl; and R.sub.1 represents hydrogen, acetyl or ethoxycarbonyl with the provisos:
(i) that n is 1 and each of the wavy lines represents a carbon-carbon single bond when R.sub.1, R.sub.2, and R.sub.6, are each hydrogen, R.sub.5, R.sub.7 and R.sub.8 are each methyl and the dashed line is a carbon-carbon single bond;
(ii) n is 0 and each of the wavy lines represents no bond when R.sub.5 and R.sub.7 are each hydrogen and R.sub.6 and R.sub.8 are each methyl;
(iii) R.sub.2 is methyl only when R.sub.1 is ethoxycarbonyl; and
(iv) the dashed line is a carbon-carbon single bond only when R.sub.1 is hydrogen.

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Guiotto et al., "Relationships Between Structure of Some Cyclohexene Derivatives and Attractiveness for the Males of Ceratitis capitata", Farmaco, 29(2), pp. 95-100 (1974).
Valega and Beroza, Journal of Economic Entomology, vol. 60, No. 2, pp. 341-347, entitled: "Structure-Activity Relationships of Some Attractants of the Mediterranean Fruit Fly"; abstracted at Chemical Abstracts, vol. 66:113455h, 1967.

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