Hydrocarbon separations

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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2606815C, C07C 716

Patent

active

040255743

ABSTRACT:
A process for the separation and recovery of unsaturated aliphatic hydrocarbons from admixture with saturated aliphatic hydrocarbons which comprises contacting such a mixture with a complexing agent comprising cuprous salts of sulfonic acids and dialkyl phosphates under such conditions that the unsaturated hydrocarbons are preferentially complexed with the cuprous salts. In one embodiment, olefins are separated from paraffins by using a cuprous sulfonate dissolved in an aromatic solvent to form a complex with the olefin. The olefin can be separated from the resulting complex and the cuprous salt recycled for reuse.

REFERENCES:
patent: 2386358 (1945-10-01), Schultze et al.
patent: 3014973 (1961-12-01), DE Vries et al.
patent: 3401112 (1968-09-01), Dunlop et al.

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