Preparation of carbamates

Organic compounds -- part of the class 532-570 series – Organic compounds – Carboxylic acid esters

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560 25, 546 88, 546260, 502339, 568 17, C07C12506, C07D47104, C07D21322

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044749783

ABSTRACT:
Process for the preparation of carbamates and/or derivatives thereof by reacting an organic compound containing at least one hydroxyl group with carbon monoxide and an organic nitrogeneous compound in the presence of a catalytic system based on palladium and a ligand according to the general formula: ##STR1## wherein L=N, P, As or Sb; R, R.sup.1, R.sup.2 and R.sup.3 are (un)substituted alkyl, aryl, alkaryl or aralkyl or R and R.sup.1 and/or R.sup.2 and R.sup.3 may form a ring together with the atom L to which they are attached; R.sup.4 and R.sup.5 are H or lower alkyl and n=2, 3 or 4, whereas carbon atoms between the groups L may be part of cyclic or non-cyclic unsaturated structures, and in the presence of an acid promoter.

REFERENCES:
patent: 3448140 (1969-06-01), Gamlen et al.
patent: 4227008 (1980-10-01), Miyata et al.
patent: 4319035 (1982-03-01), Merger et al.
patent: 4411820 (1983-10-01), Pretzer et al.

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