Propylene oxide by direct oxidation in chlorobenzene and halocar

Details Propylene oxide by direct oxidation in chlorobenzene and halocar Propylene oxide by direct oxidation in chlorobenzene and halocar

1983-04-21

1984-10-02

Milestone, Norma S.

Organic compounds -- part of the class 532-570 series

Organic compounds

Heterocyclic carbon compounds containing a hetero ring...

C07D30106

Patent

active

044749740

ABSTRACT:
A process for the direct oxidation of propylene in the presence of oxygen, a silver catalyst and chlorobenzene as a solvent is described. Halocarbon co-solvents such as trichlorotrifluoroethane are used to enhance selectivity to the desired propylene oxide. The direct oxidation is preferably run at a temperature between about 150.degree. to 250.degree. C.

REFERENCES:
patent: 3222382 (1965-12-01), Lanthier
patent: 3238229 (1966-03-01), Reid
patent: 3674813 (1972-07-01), Bljumberg et al.
patent: 3957690 (1976-05-01), Bobolev et al.
patent: 4046783 (1977-09-01), Cavitt

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