Process for the decarbonylation of an alkyl formate to form carb

Details Process for the decarbonylation of an alkyl formate to form carb Process for the decarbonylation of an alkyl formate to form carb

1984-01-09

1984-10-02

Thomas, Earl C.

Chemistry of inorganic compounds

Carbon or compound thereof

Oxygen containing

568876, C01B 3118, C07C 3104

Patent

active

044747446

ABSTRACT:
An alcohol and carbon monoxide are produced by the decarbonylation of an alkyl formate in the presence of, as catalyst, (i) a Lewis base and epoxide or (2) an amidine or a guanidine. When the Lewis base used is a trivalent phosphorus compound, for example a phosphine, it is preferable to have alcohol present at the start of the reaction.

REFERENCES:
patent: 3812210 (1974-05-01), Higdon et al.
patent: 4303630 (1981-12-01), Sano et al.
patent: 4319050 (1982-03-01), Doyle

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