Method for intercalating organic-swelled layered metal chalcogen

Catalyst – solid sorbent – or support therefor: product or process – Catalyst or precursor therefor – Silicon containing or process of making

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B01J 2106, B01J 2010

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active

049295870

ABSTRACT:
Organic-swelled layered metal chalcogenide is intercalated with polymeric chalcogenide by contacting with a hydrolyzable polymeric chalcogenide precursor under an inert atmosphere, e.g., nitrogen to minimize formation of extralaminar polymeric chalcogenide. The chalcogenide precursor is then hydrolyzed.

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A. F. Reid et al., "A New Class of Compounds", Acta Cryst (1963), B24, 1228.
W. A. England et al., "Ion Exchange in the Cs.sub.x [Ti.sub.2 -x.sub.2 MgX.sub.2 ]O.sub.4 Structure", Journal of Solid State Chemistry 49, 300-308 (1983).
I. E. Grey et al., "The Stability and Structure of C.sub.s [i.sub.2 -x/4 x/4]O.sub.7, 0.61<x<0.65", Journal of Solid State Chemistry, 66, 7-19 (1987).

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