Process for preparing adrenochrome

Details Process for preparing adrenochrome Process for preparing adrenochrome

1982-09-13

1985-02-26

Daus, Donald G.

Organic compounds -- part of the class 532-570 series

Organic compounds

Heterocyclic carbon compounds containing a hetero ring...

C07D20936

Patent

active

045019231

ABSTRACT:
A process is described for preparing adrenochrome comprising oxidizing adrenaline or a salt thereof with a persulfate in an aqueous medium at a pH in the range 4 to 8 in the presence of one or more water-soluble salts of bismuth.

REFERENCES:
patent: 3708431 (1973-01-01), Prussin
patent: 4010872 (1977-03-01), Lozano
Seiyama, et al., "Oxidative Dehydroaromatization", J. of Catalysis, vol. 24, pp. 76-81, (1972).
Nakajima, et al., "Adrenochrome Derivatives", Chem. Abst., 88: 89518n, (1977).
Wellman, et al., "Indirect Electrochemical Processes", Chem. Abst., 88: 29563(p), (1978).
Perumal, et al., "Oxidation of Aromatic Substrates", Chem. Abst., 92: 198135(p), (1979).
Marsheck, Robt., "Cyclic Oxidative Dehydrogenation . . . ", Chem. Abst., 95: 42321(x), (1981).

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