Process for the hydroxylation of olefins using molecular oxygen,

Details Process for the hydroxylation of olefins using molecular oxygen, Process for the hydroxylation of olefins using molecular oxygen,

1984-04-26

1985-01-29

Evans, J. E.

Organic compounds -- part of the class 532-570 series

Organic compounds

Oxygen containing

2603972, 560186, 562587, 568811, 568821, 568833, 568838, 568847, C07C 2904, C07C 3118, C07C 3122, C07C 3142

Patent

active

044967799

ABSTRACT:
A process directed to the hydroxylation of olefins by reacting said olefins in the presence of oxygen, water, and a catalyst composition comprising (i) a catalytically active osmium containing compound, (ii) a Co-catalyst I comprising a copper containing compound such as CuBr.sub.2, and (iii) a Co-catalyst II capable of increasing the rate and/or selectivity of the hydroxylation reaction, such as 1,4-diazabicyclo [2.2.2.] octane is disclosed.

REFERENCES:
patent: 2773101 (1956-12-01), Smith et al.
patent: 3317592 (1967-05-01), Maclean et al.
patent: 3337635 (1967-08-01), Norton et al.
patent: 4390739 (1983-06-01), Michaelson et al.

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