Production of epoxy compounds from olefinic compounds

Organic compounds -- part of the class 532-570 series – Organic compounds – Heterocyclic carbon compounds containing a hetero ring...

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549520, 549522, 204 80, C07D30126, C25B 146, C25B 302

Patent

active

044967527

ABSTRACT:
Chlorine and tertiary alkanol dissolved in an inert organic solvent are reacted with aqueous alkali to produce tertiary alkyl hypochlorite which is recovered in the organic solvent and reacted with water and olefinically unsaturated compound to produce chlorohydrin and tertiary alkanol. Chlorohydrin and tertiary alkanol recovered in the organic solvent are contacted with aqueous alkali to produce the epoxy compound, and tertiary alkanol recovered in the organic solvent is recycled to hypochlorite production. The process may be integrated with the electrolytic production of chlorine, with an appropriate treatment of the recycle aqueous stream when required.

REFERENCES:
patent: 2694722 (1954-11-01), Katz
patent: 4008133 (1977-02-01), Gelbein et al.
patent: 4126526 (1978-11-01), Kown et al.

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