Production of chlorine dioxide

Chemistry of inorganic compounds – Halogen or compound thereof – Chlorine dioxide

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C01B 1102

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active

049312685

ABSTRACT:
Chlorine dioxide is generated at high efficiency from feeds of chlorate cell liquor, sulphuric acid and methanol by a hybrid of reaction of sodium chlorate with sulphuric acid and methanol and reaction of sodium chlorate with sulphuric acid and sodium chloride. The reaction medium is maintained at its boiling point under a subatmospheric pressure while sodium sesquisulphate precipitates from the reaction medium.

REFERENCES:
patent: 3427236 (1969-02-01), Scholander et al.
patent: 4156713 (1979-05-01), Fuller
patent: 4465658 (1984-08-01), Fredette
patent: 4473540 (1984-09-01), Fredette
patent: 4627969 (1986-12-01), Fredette et al.

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