Compositions – Preservative agents – Anti-oxidants or chemical change inhibitants
Patent
1981-09-14
1983-08-02
Gantz, Delbert E.
Compositions
Preservative agents
Anti-oxidants or chemical change inhibitants
252435, B01J 2714
Patent
active
043965369
ABSTRACT:
The present invention provides a process for the preparation of oxidation catalysts containing mixed oxides of vanadium and phosphorus, which catalysts are particularly effective in the oxidation of n-butane, n-butenes, 1,3-butadiene or a mixture thereof with molecular oxygen or an oxygen-containing gas in the vapor phase to produce high yields of maleic anhydride with good selectivity. A vanadium compound is introduced into an olefinic oxygenated organic liquid medium, a phosphorus-containing compound is added to the medium, reduction of at least a portion of the vanadium to a +4 valence state is effected either prior to or subsequent to the addition of the phosphorus-containing compound, and the resulting vanadium-phosphorus oxide catalyst precursor is recovered, dried and calcined.
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Bremer Noel J.
Dria Dennis E.
Curatolo Joseph G.
Evans Larry W.
Gantz Delbert E.
Knudsen Herbert D.
The Standard Oil Company
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