Catalyst – solid sorbent – or support therefor: product or process – Catalyst or precursor therefor – Plural component system comprising a - group i to iv metal...
Patent
1986-08-07
1987-04-28
Garvin, Patrick P.
Catalyst, solid sorbent, or support therefor: product or process
Catalyst or precursor therefor
Plural component system comprising a - group i to iv metal...
502115, 502125, 526125, 526142, C08F 462, C08F 464, C08F 468
Patent
active
046614656
ABSTRACT:
A method for preparing Ziegler catalysts is disclosed wherein a mixture (A) containing the product resulting from mixing in an inert hydrocarbon diluent (1) a hydrocarbon soluble magnesium alkyl compound in said hydrocarbon solvent, (2) an aliphatic alcohol or carbon dioxide and (3) a titanium compound is reacted with (B) a reducing halide source in said hydrocarbon solvent. Components (A) and (B) are mixed at a constant initial temperature. When the magnesium concentration in component (A) and the metal concentration in component (B) are relatively low, the resultant polymer has a relatively narrow particle size distribution whereas when said concentration is relatively high, the resultant polymer has a relatively broad particle size distribution. When the ratio of the number of moles of aliphatic alcohol:total number of hydrocarbyl groups attached to the metal atom in component (1) is relatively low, the resultant polymer has a relatively small average particle size. When the ratio of the number of moles of aliphatic alcohol:total number of hydrocarbyl groups attached to the metal atom in component (1) is relatively high, the resultant polymer has a relatively large average particle size.
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Fuentes, Jr. Ricardo
Marchand Gary R.
Meiske Larry A.
Carter James G.
Garvin Patrick P.
The Dow Chemical Company
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