Preparation of HNS from HNBB using oxygen

Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing

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C07C 7910

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active

042700124

ABSTRACT:
A process for preparing 2,2',4,4',6,6'-hexanitrostilbene in high yields by eacting 2,2',4,4',6,6'-hexanitrobibenzyl in a suitable solvent with an oxygen-containing gas in the presence of a catalyst. The catalyst is selected from the group consisting of copper ammino and cobalt ammino compounds, copper and cobalt acetates, copper and cobalt halides, copper sulfate, and ammonium and alkali metal bases.

REFERENCES:
patent: 3505413 (1970-04-01), Shipp
patent: 3716590 (1973-02-01), Caraculacu et al.
patent: 3895055 (1975-07-01), Itatani
patent: 4085152 (1978-04-01), Salter et al.

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