Hole cleaning process for printed circuit boards using permangan

Coating processes – Electrical product produced – Integrated circuit – printed circuit – or circuit board

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134 29, 134 2216, 134 2217, 156655, 156668, 156902, 252 795, 427 98, 427307, B05D 512, B05D 304, B29C 1708, B44C 122

Patent

active

044253800

ABSTRACT:
An improved process for removing resin smeared on an interior wall of a hole in a resinous substrate and/or adhesion promoting the substrate which comprises: (a) contacting the substrate with an alkaline permanganate treating solution having a pH between about 11 and about 13 and an elevated temperature for a time period sufficient to remove the resin smear; (b) neutralizing essentially all manganese residue on the substrate; (c) contacting the substrate with an alkaline hydroxide etchant to remove the balance of manganese residue on the substrate. A metal such as copper subsequently may be electrolessly deposited in a more efficient and easily controlled manner on the resin substrate in the formation of a wire scribed circuit board or multilayer printed circuit board. In addition to resin smear removal, the process results in an improved bond between copper and the hole wall.

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Bulletin De L'Academie Polonaise Des Sciences, vol. VII, No. 6, 1959, Kinetics and Mechanism of Reduction of Permanganate to Manganate by OH-Ions by B. Jezowska-Trzebiatowska et al., pp. 405-420.

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