Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing
Patent
1978-09-13
1980-05-20
Sebastian, Leland A.
Organic compounds -- part of the class 532-570 series
Organic compounds
Oxygen containing
568939, C07C 3304
Patent
active
042040787
ABSTRACT:
Nitrophenylacetylene and certain precursors to nitrophenylacetylene are prepared in improved yields by reacting a nitrobromobenzene with a substituted terminal acetylene compound containing at least three carbon atoms and a hydroxy group on the carbon atom adjacent to the acetylene group in the presence of a dialkyl or trialkyl amine solvent and a catalyst system consisting of a palladium complex containing two halogen moieties and two tri-substituted phosphine moieties and some excess trisubstituted phosphine compounds.
REFERENCES:
patent: 4016214 (1977-04-01), Douglas et al.
Sabourin Edward T.
Selwitz Charles M.
Gulf Research & Development Company
Sebastian Leland A.
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