Method for the preparation of beta-substituted allylsilane

Organic compounds -- part of the class 532-570 series – Organic compounds – Silicon containing

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C07F 708

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048989592

ABSTRACT:
Beta-substituted allylsilanes are synthesized in a one-step process from readily available starting materials by the reaction of a specific carboxylic acid ester or acid anhydride with a specific alkoxy group-containing Grignard reagent in an organic solvent. The resulting allylsilanes are useful as allyl transfer reagents for electrophilic reagents such as ketones, carboxylic acid chlorides, etc.

REFERENCES:
patent: 3223686 (1965-12-01), Matta et al.

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