Continuous preparation of polyoxybutylene polyoxyalkylene glycol

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – From heterocyclic reactant containing as ring atoms oxygen,...

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Other Related Categories

528417, 560240, 568617, C08G 6520

Type

Patent

Status

active

Patent number

045646716

Description

ABSTRACT:
Polyoxybutylene polyoxyalkylene glycols are prepared by copolymerization of tetrahydrofuran with a 1,2-alkylene oxide in the presence of a compound containing reactive hydrogen, by a continuous process in which the polymerization is carried out in a reactor over a fixed-bed clay catalyst and with recycling of the reaction mixture, and less than 30% by weight, based on the reaction mixture to be recycled, of a mixture of tetrahydrofuran, 1,2-alkylene oxide and a compound containing reactive hydrogen is added to the reaction mixture, which is recycled to the reactor after flowing through the latter.

REFERENCES:
patent: 4127513 (1978-11-01), Bellis
patent: 4189566 (1980-02-01), Mueller et al.
patent: 4192943 (1980-03-01), Robinson
patent: 4228272 (1980-10-01), Del Pesco
patent: 4303782 (1981-12-01), McHale et al.
Ullmann's Enzyklopadie der technischen chemie, 3rd ed., vol. IV, pp. 541-545.

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